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Article

Reversible disorder-order transitions in atomic crystal nucleation
Author Jeon, Sungho; Heo, Taeyeong; Hwang, Sang-Yeon; Ciston, Jim; Bustillo, Karen C.; Reed, Bryan W.; Ham, Jimin; Kang, Sungsu; Kim, Sungin; Lim, Joowon; Lim, Kitaek; Kim, Ji Soo; Kang, Min-Ho; Bloom, Ruth S.; Hong, Sukjoon; Kim, Kwanpyo; Zettl, Alex; Kim, Woo
Corresponding Author Info Prof. Lee, Won Chul (±â°è°øÇаú)
Professor
À̹ÌÁö
E-mail ¸ÞÀÏwonchullee@hanyang.ac.kr
Document Type
Source Science 2021, 371, 6528, 498
Times Cited 21 (2022.2.21.)
External Information pdfhttps://www.science.org/doi/10.1126/science.aaz7555
Abstract
[History]
- 2021³â July/AugustºÎ·Î, ÀÌ highly cited paper ÀÇ Àοë Ƚ¼ö°¡ ºÐ¾ß¿Í ÃâÆÇ ¿¬µµ¿¡ ´ëÇØ ÀÎ¿ë ºóµµ°¡ ³ôÀº ÀÓ°è°ªÀ» ±â¹ÝÀ¸·Î Chemistry Çмú ºÐ¾ß¿¡¼­ »óÀ§ 1%¿¡ ¿Ã¶ú½À´Ï´Ù.

[Abstract]
Nucleation in atomic crystallization remains poorly understood, despite advances in classical nucleation theory. The nucleation process has been described to involve a nonclassical mechanism that includes a spontaneous transition from disordered to crystalline states, but a detailed understanding of dynamics requires further investigation. In situ electron microscopy of heterogeneous nucleation of individual gold nanocrystals with millisecond temporal resolution shows that the early stage of atomic crystallization proceeds through dynamic structural fluctuations between disordered and crystalline states, rather than through a single irreversible transition. Our experimental and theoretical analyses support the idea that structural fluctuations originate from size-dependent thermodynamic stability of the two states in atomic dusters. These findings, based on dynamics in a real atomic system, reshape and improve our understanding of nucleation mechanisms in atomic crystallization.
Web of Science Categories Multidisciplinary Sciences
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